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- Organometallic Reagents, Reactivity and Basicity. 醇的合成(已知方法和新的策略)。
- Triethylborane can be synthesized at a stroke by organometallic route with the aid of ultrasound. 用超聲波通過(guò)有機金屬路線(xiàn)一步合成三乙基硼,產(chǎn)率高達79.;2%25,反應時(shí)間大大縮短。
- The organometallic compounds - catalyzed cyclization reactions in syntheses of carbo -and heterocycles are reviewed. 綜述了近年來(lái)金屬有機化合物催化的環(huán)化反應在合成碳20環(huán)及雜環(huán)化合物中的應用。
- Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley: New York, 2000. 許智能,國立中山大學(xué)化學(xué)研究所博士論文,民國八十七年。
- The process has been shown to be applicable to a variety of both aldehydes and organometallic reagents. 過(guò)程一直表現得既適用于各種有機醛試劑.
- The discovery of ferrocene plays an important role in quick development of organometallic chemistry. 二茂鐵的發(fā)現對金屬有機化學(xué)的迅速發(fā)展起著(zhù)舉足輕重的作用。
- Possible applications of the organometallic complex doped inorganic materials have been studied. 探索研究了金屬有機配合物摻雜無(wú)機固態(tài)材料的潛在用途。
- Over the past decades, various efficient methods based on organometallic homogeneous catalysts have been developed. 在過(guò)去的三十多年里,合成化學(xué)家們將更多的目光集中到金屬有機化合物均相催化劑上,設計合成了許多金屬配合物催化劑。
- Over the past decades, various efficient methods based on organometallic catalysts have been established. 在過(guò)去三十多年中,合成化學(xué)家發(fā)現金屬有機催化劑對許多反應有著(zhù)良好的催化效果。
- Tremendous advances have been made in the design and application of organometallic complexes as olefin polymerization in the past decades. 論述了烯烴聚合催化劑的發(fā)展更新過(guò)程,催化聚合的過(guò)程。
- A blue violet laser is described by direct laser diode frequency doubling with a new nonlinear organometallic complex CMTC crystal. 報道了用新型絡(luò )合物非線(xiàn)性光學(xué)材料硫氰酸汞鎘(CMTC)晶體實(shí)現激光二極管室溫下直接倍頻,產(chǎn)生藍紫光激光輸出。
- Study for no-cyclopentadienyl organometallic catalysts is hotspot at present and the search for new catalysts is far from over. 涉及配位聚合的鏈增長(cháng)機理、單體幾種可能的插入模式及聚合的立構控制方式、鏈轉移或鏈終止機理以及可能存在的催化活性中心的失活過(guò)程。
- The recent advance of the synthesis and characterization of rare earth organometallic complexes involving cyclopentadienyl types is reviewed. 本文綜述了茂型稀土金屬有機配合物的研究現狀和最新進(jìn)展。
- Aqueous allylation reaction mediated by metals is one of the most widely researched organometallic reactions in aqueous media. 在已發(fā)現的水相金屬有機反應中,水相烯丙基化反應是研究得較多和較深入的反應之一。
- The chemistry of cyclopentadiene organometallic complexesincluding the syntheses properties and applications are discussed in detail. 較全面敘述了環(huán)戊二烯(茂)金屬配合物的化學(xué)和應用。包括配位體環(huán)戊二烯的合成和性質(zhì)。
- Organometallic chelates are seen as the best electroluminescent (EL) materials in OEFPD for their excellent EL properties. 有機金屬螯合物因其優(yōu)良的電致發(fā)光性能,被首選為有機電致發(fā)光平板顯示器的發(fā)光材料。
- Finally, the prospects of rare earth organometallic chemistry involving cyclopentadienyl types in the future are described. 最后,展望其發(fā)展趨勢和研究方向。
- Ferrocene is a compound with special structure, and its discovery has landmark meaning in study of organometallic compounds. 二茂鐵是一種結構很特殊的化合物,它的發(fā)現在金屬有機化合物研究中具有里程碑意義。
- Cyclopentadienyl type organometallic compound can activate CO which prohibits the formation of the precursor of the soot. 茂型金屬有機物能活化CO分子,進(jìn)而有效抑止炭煙先導物的生成。
- The polymerization of ethylene oxide was carried out with catalysts of many components whose main components were organometallic compounds. 采用有機金屬化合物為主體的多組分催化劑進(jìn)行環(huán)氧乙烷的聚合試驗。