The effect of potential scan direction and range, the presence of N_2 and O_2, electrolyte, the concentration of NaOH, KBr and fluorescein on fluorescein ECL was examined.
英
美
- 除ECL-3以外的所有發(fā)光峰都是由于熒光素的電氧化或熒光素與溶液中不同電位下電生成的物質(zhì)之間發(fā)生反應產(chǎn)生(~1O_2~*)_2，(~1O_2~*)_2將能量傳遞給溶液中的熒光基團如熒光素或由熒光素電解生成的曙紅Y，產(chǎn)生光發(fā)射。
