The bulkily substituted zirconocene dichloride complexes of the type RCpCpoZrCl2 [Cpo=2-MeOArCR1R2Cp, R1, R2 = CH3, C2H5, (CH2)5, etc.] have been synthesized by the reaction of 6,6-dialkylfulvene with 2-MeOArLi followed by treatment with RCpZrCl3?
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美
- 通過(guò)6；6-二烷基富烯與2-MeOArLi進(jìn)行加成反應；得到含芳氧取代的環(huán)戊二烯基鋰鹽；再與取代茂三氯化鋯反應；合成了不對稱(chēng)大位阻取代茂鋯配合物RCpCpoZrCl2[Cpo=2-MeOArCR_1R_2C_p；R_1；R_2=CH_3；C_2H_5；(CH_2)_5；etc.；]
