The absorption edge increases as the amount of fluorine is raised. The optical energy gap E g is mainly determined by CF bond in the films, which results in the change of the density of states in band tail of the valence band.

 
  • 薄膜中氟的引入對吸收邊和光學(xué)帶隙產(chǎn)生較大的影響 ,吸收邊隨氟含量的提高而增大 ,光學(xué)帶隙則主要取決于CF鍵的含量 ,是由于強電負性F的引入改變了價(jià)帶帶尾附近帶隙中態(tài)密度的結果所至
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