Polynuclear complexes containing N and S atoms [M (Fc-C(CH3)= NN = CSSR)2,R=-CH3, -CH2C6H5, M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+] were synthesized. It was found that the coordination compounds could quench *Ru(bpy)32+ with high efficiency.
英
美
- 合成了Co~(2+)、Ni~(2+)、Cu~(2+)、Cd~(2+)、Zn~(2+)等金屬的Schiff堿型二茂鐵基多核配合物,并對其進(jìn)行元素分析和光譜表征,發(fā)現該類(lèi)配合物能有效地猝滅Ru(bpy)~(2+)_3發(fā)光。
