In this paper an equation of reaction speed determined by the experiment is deduced from the composition of the activated complex form the basic assumption of transition-state theory and the basic porperties of thermodynamic equilibrium.
英
美
- 從過(guò)渡狀態(tài)理論的基本假設出發(fā),結合熱力學(xué)平衡及反應速率控制步驟的基本性質(zhì),本文提出通過(guò)由實(shí)驗確定的某化學(xué)反應的反應速率方程來(lái)推算該反應活化絡(luò )合物組成的簡(jiǎn)便可行的方法。
